John Humphrys
Ali interviews John Humphrys, presents his home shopping channel, QVG, and helps Fran Healy from Travis give 'Why Does It Always Rain on Me?' an urban twist, while Borat learns about British comedy.
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More from this season
S1 E1
Neil Hamilton
Ali travels to the Cannes Film Festival, to pitch his new movie 'Booka' - named after the noise a gun makes. There's a lively discussion on animal rights, Neil Hamilton joins Ali on the sofa and the first ever contestant plays 'Who Wants to Win an Ounce?'. Elsewhere, Borat learns about British etiquette.
S1 E2
Mohamed Al Fayed
Ali gets the low-down on the FB, Aiiii. There's rapping from Mohammed Al Fayed, and Borat finds out what it takes to be a true British huntsman.
S1 E3
Gail Porter
Ali learns how to save the environment - and use guns to kill people. Later, he serenades the lovely Gail Porter, and Borat joins Cambridge University's young intelligentsia for a game of cricket.
S1 E4
Roy Hattersley
It's up to Ali G to turn the tables in the Third World - with turntables. Ali goes behind the scenes of US TV, and Roy Hattersley and Chrissie Hynde join Ali on the show.